Fullerene
Definition: A class of cage-like carbon compounds composed of fused, pentagonal and/or hexagonal sp2 carbon rings.
Related NanoWords
• Buckminsterfullerene
• Buckyball
• Chemistry
• Nanotube  

Used in Context
•  Fullerene Chemistry
•  Fullerene Patent Database
•  AEM on Carbon Allotropes
•  Fused Ring Nomenclature  

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Fullerenes were first discovered in 1985 when the the soccer ball shaped C60 (Buckminsterfullerene) was synthesized. The carbon atoms in C60 are arranged in a geometric shape consisting of 12 pentagons and 20 hexagons. Other spherical fullerenes (collectively known as buckyballs) were subsequently synthesized with a different number of hexagonal faces. The smallest possible fullerene is the dodecahedral C20, a shape consisting of 12 pentagonal faces and no hexagonal faces [1]. Larger, fullerenes have been found to exist in nature [2]. Nanotubes, nanohorns and buckybowls are other examples of fullerenes.

More Definitions of Fullerene:

"Though there tends to be some variation in definitions of fullerenes and related structures, generally buckminsterfullerene, or the buckyball, is taken to refer only to C60, an approximately spherical, hollow, carbon molecule containing 60 carbon atoms arranged in interlocking hexagons and pentagons, akin to the geodesic dome created by architect Buckminster Fuller, hence the name. The structure also looks very much like a soccer ball. The other fullerenes are similar cage-like molecules with more or less carbon atoms, but still composed of pentagons and hexagons. The remaining fullerenes contain more or less carbon atoms, again arranged in pentagons and hexagons." - CMP-Cientifica

"A closed, convex cage molecule containing only hexagonal and pentagonal faces. (This definition intentionally leaves out possible heptagons, which are responsible for the concave parts and are treated as defects.)" - Boris I. Yakobson and Richard E. Smalley

References:

[1] H. Prinzbach, A. Weiler, P. Landenberger, F. Wahl, J. Wšrth, L. T. Scott, M. Gelmont, D. Olevano & B. V. Issendorff, "Gas-phase production and photoelectron spectroscopy of the smallest fullerene, C20," (2000) Nature, 407, 60 - 63. Abstract

[2] L. Becker, R.J. Poreda, T. E. "Fullerenes: An extraterrestrial carbon carrier phase for noble gases", (2000) Proc. Natl. Acad. Sci. USA, 97, 7, 2979-2983. Abstract

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